Jen wore her hair in an updo, which put her striking tiara front and centre. She accessorised with some drop earrings featuring large ruby gemstones.
Of course Jennifer wasn't the only famous face to witness the runway in Venice.
A slew of other celebrities including Helen Mirren, Lady Kitty Spencer and January Jones joined the elite guest list.
Mirren, 76, looked incredible in a glimmering silver gown.
Meanwhile Princess Diana's newly married niece Lady Kitty was spotted in a stunning strapless cream gown featuring embroided florals across the bodice and skirt—again, a reflection of the label's iconic aesthetic.
The 30-year-old is no stranger to a D&G moment in Italy—last month she married her parter Michael Lewis in no less than five breathtaking designs by the fashion house.